A Condensed Gas-Phase Chemical Model and Its Application

Wang Tijian; Sun Zhaobo; Li Zongkai

doi:10.1007/s00376-999-0035-y

Impact Factor: 5.8

Volume 16 Issue 4

Oct. 1999

Article Contents

Article > ADVANCES IN ATMOSPHERIC SCIENCES > 1999 > 16(4): 608-618

A Condensed Gas-Phase Chemical Model and Its Application

1.
Department of Atmospheric Sciences, Nanjing University, Nanjing 210093,Nanjing Institute of Meteorology, Nanjing 210044,Department of Atmospheric Sciences, Nanjing University, Nanjing 210093

doi: 10.1007/s00376-999-0035-y

Abstract
References
Related papers
PDF

Abstract:
Using the “lumped mechanism” and “counting species” methods, we developed a condensed gas-phase chemical model based on a simplified one. The modified quasi-steady-state approximation (QSSA) scheme and the error redistribution mass conservation technique are adopted to solve the atmospheric chemistry ki-netic equations. Results show that the condensed model can well simulate concentration variations of gas species such as SO2, NOx, O3, H2O2 and conversion rates of SO2 and NOx, transformation to H2SO4 and HNO3. These results are in good agreement with those from the simplified model, The conversion rates of SO2 and NOx under different initial concentrations and meteorological conditions are computed, and the results can be directly applied to regional acid deposition model.
- Gas-phase chemistry,
- Conversion rate
References

[1]	MA Jianzhong, XU Xiaobin, ZHAO Chunsheng, YAN Peng, 2012: A Review of Atmospheric Chemistry Research in China: Photochemical Smog, Haze Pollution, and Gas-Aerosol Interactions, ADVANCES IN ATMOSPHERIC SCIENCES, 29, 1006-1026. doi: 10.1007/s00376-012-1188-7
[2]	Liu Xuanfei, Zhu Qiangen, Guo Pinwen, 2000: Conversion Characteristics between Barotropic and Baroclinic Circulations of the SAH in Its Seasonal Evolution, ADVANCES IN ATMOSPHERIC SCIENCES, 17, 129-139. doi: 10.1007/s00376-000-0049-y
[3]	Zeinab SALAH, Ahmed SHALABY, Allison L. STEINER, Ashraf S. ZAKEY, Ritesh GAUTAM, Mohamed M. ABDEL WAHAB, 2018: Study of Aerosol Direct and Indirect Effects and Auto-conversion Processes over the West African Monsoon Region Using a Regional Climate Model, ADVANCES IN ATMOSPHERIC SCIENCES, 35, 182-194. doi: 10.1007/s00376-017-7077-3
[4]	Xu Jianjun, 1993: Quasi-40-Day Oscillation and Its Teleconnection Struc-ture together with the Possible Dependence on Conversion of Barotropic Unstable Energy of Temporal Mean Flow, ADVANCES IN ATMOSPHERIC SCIENCES, 10, 193-200. doi: 10.1007/BF02919141
[5]	LI Yuefeng, 2007: Conversion of Kinetic Energy from Synoptic Scale Disturbance to Low-Frequency Fluctuation over the Yangtze River Valley in the Summers of 1997 and 1999, ADVANCES IN ATMOSPHERIC SCIENCES, 24, 591-598. doi: 10.1007/s00376-007-0591-y
[6]	LIU Chengyan* and WANG Zhaomin, , 2014: On the Response of the Global Subduction Rate to Global Warming in Coupled Climate Models, ADVANCES IN ATMOSPHERIC SCIENCES, 31, 211-218. doi: 10.1007/s00376-013-2323-9
[7]	Lan Hongdi, Jiang Maoji, 1985: RESEARCH ON THE PHOTO-TEMPERATURE MODEL FOR THE DEVELOPMENTAL RATE OF RICE, ADVANCES IN ATMOSPHERIC SCIENCES, 2, 549-552. doi: 10.1007/BF02678753
[8]	Xu Li, Shi Guangyu, 1985: AN EXACT CALCULATION OF INFRARED COOLING RATE DUE TO WATER VAPOR, ADVANCES IN ATMOSPHERIC SCIENCES, 2, 531-541. doi: 10.1007/BF02678751
[9]	Ma Zhenhua, Liu Guosheng, Liu Wei, 1985: PRINCIPAL STUDY OF THE FM RADAR FOR IMPROVING THE ACCURACY IN QUANTITATIVE RAINFALL RATE MEASUREMENT, ADVANCES IN ATMOSPHERIC SCIENCES, 2, 341-346. doi: 10.1007/BF02677250
[10]	Li Guoqing, Robin Kung, Richard L. Pfeffer, 1993: Some Effects of Rotation Rate on Planetary-Scale Wave Flows, ADVANCES IN ATMOSPHERIC SCIENCES, 10, 296-306. doi: 10.1007/BF02658135
[11]	Zhang Renjian, Wang Mingxing, 1999: Modeling the Sudden Decrease in CH4 Growth Rate in 1992, ADVANCES IN ATMOSPHERIC SCIENCES, 16, 242-250. doi: 10.1007/BF02973085
[12]	Xinyi XING, Xianghui FANG, Da PANG, Chaopeng JI, 2024: Seasonal Variation of the Sea Surface Temperature Growth Rate of ENSO, ADVANCES IN ATMOSPHERIC SCIENCES, 41, 465-477. doi: 10.1007/s00376-023-3005-x
[13]	Zhang Ming, Zhang Lifeng, 2002: Semi-Circle Theorem of Unstable Spectrum Distribution of Heterotropic Perturbation and the Upper Bound Estimation of Its Growth Rate, ADVANCES IN ATMOSPHERIC SCIENCES, 19, 35-44. doi: 10.1007/s00376-002-0032-x
[14]	HU Liang, LI Yaodong, DENG Difei, 2013: An Investigation into the Relationship between Surface Rain Rate and Rain Depth over Southeast Asia, ADVANCES IN ATMOSPHERIC SCIENCES, 30, 142-152. doi: 10.1007/s00376-012-2097-5
[15]	Peng LIU, Jianning SUN, Lidu SHEN, 2016: Parameterization of Sheared Entrainment in a Well-developed CBL. Part II: A Simple Model for Predicting the Growth Rate of the CBL, ADVANCES IN ATMOSPHERIC SCIENCES, 33, 1185-1198. doi: 10.1007/s00376-016-5209-9
[16]	Shi LUO, Chunsong LU, Yangang LIU, Yaohui LI, Wenhua GAO, Yujun QIU, Xiaoqi XU, Junjun LI, Lei ZHU, Yuan WANG, Junjie WU, Xinlin YANG, 2022: Relationships between Cloud Droplet Spectral Relative Dispersion and Entrainment Rate and Their Impacting Factors, ADVANCES IN ATMOSPHERIC SCIENCES, 39, 2087-2106. doi: 10.1007/s00376-022-1419-5
[17]	Lei ZHU, Chunsong LU, Xiaoqi XU, Xin HE, Junjun LI, Shi LUO, Yuan WANG, Fan WANG, 2024: The Probability Density Function Related to Shallow Cumulus Entrainment Rate and Its Influencing Factors in a Large-Eddy Simulation, ADVANCES IN ATMOSPHERIC SCIENCES, 41, 173-187. doi: 10.1007/s00376-023-2357-6
[18]	Ma Zhenhua, 1985: THE EFFECTS OF EARTH PARTIAL SPECULAR REFLECTION ON THE QUANTITATIVE RAINFALL-RATE MEASUREMENTS BY RADAR, ADVANCES IN ATMOSPHERIC SCIENCES, 2, 104-111. doi: 10.1007/BF03179742
[19]	Bian Jianchun, Chen Hongbin, Sun Haibing, Yang Peicai, Lu Daren, Zhou Xiuji, 1999: Retrievals of Rain-Rate over Oceans from SSM/ I Data Using SOM Model, ADVANCES IN ATMOSPHERIC SCIENCES, 16, 355-360. doi: 10.1007/s00376-999-0014-3
[20]	GONG Youguo, SU Hang, CHENG Yafang, LIU Feng, WU Zhijun, HU Min, ZENG Limin, ZHANG Yuanhang, 2008: Analysis on Concentration and Source Rate of Precursor Vapors Participating in Particle Formation and Growth at Xinken in the Pearl River Delta of China, ADVANCES IN ATMOSPHERIC SCIENCES, 25, 427-436. doi: 10.1007/s00376-008-0427-4

PDF

Get Citation+

Export:

Article Metrics

Article Views: 1406 Times

PDF downloads: 1050 Times

Cited by: Times

Proportional views

Manuscript History

Manuscript received: 10 October 1999

Manuscript revised: 10 October 1999

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A Condensed Gas-Phase Chemical Model and Its Application

1. Department of Atmospheric Sciences, Nanjing University, Nanjing 210093,Nanjing Institute of Meteorology, Nanjing 210044,Department of Atmospheric Sciences, Nanjing University, Nanjing 210093

Manuscript received: 1999-10-10
Manuscript revised: 1999-10-10

Abstract: Using the “lumped mechanism” and “counting species” methods, we developed a condensed gas-phase chemical model based on a simplified one. The modified quasi-steady-state approximation (QSSA) scheme and the error redistribution mass conservation technique are adopted to solve the atmospheric chemistry ki-netic equations. Results show that the condensed model can well simulate concentration variations of gas species such as SO2, NOx, O3, H2O2 and conversion rates of SO2 and NOx, transformation to H2SO4 and HNO3. These results are in good agreement with those from the simplified model, The conversion rates of SO2 and NOx under different initial concentrations and meteorological conditions are computed, and the results can be directly applied to regional acid deposition model.

Keywords: