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新疆天山地区夏季大气气溶胶粒径分布和云凝结核活化特征

Characteristics of Aerosol Particle Size Distribution and Cloud Condensation Nuclei Activation during Summer in the Tianshan Mountains in Xinjiang

  • 摘要: 2019年8月4~25日使用气溶胶宽范围粒径谱仪和云凝结核计数器观测获得了新疆中天山地区气溶胶和云凝结核(CCN)数浓度数据,结合气象要素资料和HYSPLIT模型,分析了CCN和气溶胶粒径分布特征及其影响因素。结果表明:在观测期间,天山气溶胶数浓度均值为3607±4105 cm−3,爱根核模态粒子占比最高(64.76%)。CCN数浓度在0.1%、0.2%、0.4%、0.6%和0.8%过饱和度下的均值分别为185±185 cm−3、648±345 cm−3、1578±1045 cm−3、2077±1417 cm−3和2408±1657 cm−3。气溶胶数浓度平均谱分布呈单峰型,峰值粒径位于29.5 nm。气溶胶数浓度日变化在08:00(北京时,下同)、17:00和20:00出现峰值,主要受边界层高度日变化、山谷风和排放源等影响。不同模态气溶胶粒子数浓度日变化不同,爱根核模态粒子呈双峰型,积聚模态粒子呈三峰型,而核模态粒子数浓度日变化呈单峰型可能与新粒子生成有关。CCN活化谱拟合结果为N=3111S0.896S为过饱和度,N为过饱和度S下CCN数浓度),属于清洁大陆型特征。CCN数浓度日变化在08:00、18:00和21:00出现峰值。新粒子生成事件有利于天山地区CCN数浓度的增加,在0.1%、0.2%、0.4%、0.6%和0.8%过饱和度下新粒子生成事件天CCN平均数浓度分别比非新粒子生成事件天高13%、18%、25%、22%和20%。相对湿度(RH)对核模态粒子数浓度影响较大,对其他模态粒子数浓度影响较小,随着RH的增加,气溶胶谱分布向大粒径方向偏移。当RH>60%时,气溶胶及CCN数浓度随RH增加均出现减少的趋势。由于地形与山谷风的影响,偏北风与偏东风下气溶胶和CCN数浓度较高。天山气团主要有西方气团(占比29.2%)、西北气团(29.3%)、东北气团(27.0%)和南方气团(14.5%)四类。由于气团来向和移动路径的不同以及北方城市带的影响,来自天山北面的东北气团气溶胶数浓度最大,为5449±3793 cm−3,南方气团最低,为1971±2087 cm−3。东北气团各过饱和度下CCN数浓度均较高,比最低的南方气团高100%~150%。

     

    Abstract: To investigate the characteristics of CCN (cloud condensation nuclei) and aerosol particle size distribution, along with their influencing factors in the Middle Tianshan region of Xinjiang, data on aerosol and CCN number concentration were collected from 4 to 25 August 2019. Measurements were conducted using an aerosol wide-range particle size spectrometer and a CCN counter, complemented by meteorological data and the HYSPLIT model for comprehensive analysis. The results revealed that during the observation period, the average aerosol number concentration in Tianshan was 3607±4105 cm−3, with Aitken mode particles accounting for the highest proportion (64.76%). The mean CCN number concentrations at supersaturation levels of 0.1%, 0.2%, 0.4%, 0.6%, and 0.8% were 185±185 cm−3, 648±345 cm−3, 1576±1045 cm−3, 2077±1417 cm−3, and 2408±1657 cm−3, respectively. The average aerosol number concentration exhibited a unimodal distribution, with the peak particle size located at 29.5 nm. Diurnal variations in aerosol number concentration showed peaks at 0800 BJT (Beijing time), 1700 BJT, and 2000 BJT, influenced primarily by the boundary layer height diurnal variation, mountain-valley winds, emission sources, and other factors. During summer, aerosol particles in the Tianshan Mountains exhibited distinct distribution modes. The Aitken mode particles exhibited a bimodal distribution, while the accumulation mode particles displayed a trimodal distribution. The number concentration of nucleation mode particles showed an unimodal diurnal variation, likely attributable to NPF (new particle formation). The CCN activation spectrum fitting yielded N=3111S0.896 (where N is the CCN number concentration at supersaturation S), characteristic of a clean continental type. The diurnal variation of CCN number concentration peaked at 0800 BJT, 1800 BJT, and 2100 BJT. NPF was found to enhance the CCN number concentration in the Tianshan Mountains. At supersaturation levels of 0.1%, 0.2%, 0.4%, 0.6%, and 0.8%, the average CCN concentrations on NPF days were respectively 13%, 18%, 25%, 22%, and 20% higher than those on non-NPF days. RH (relative humidity) had a more significant impact on the concentration of nucleation mode particles compared with other particle modes. As RH increased, the aerosol size distribution shifted toward larger particle sizes. When RH exceeded 60%, the number of concentrations of both aerosols and CCN decreased with increasing RH. Additionally, aerosol and CCN number concentrations were higher under northerly and easterly winds, influenced by the region’s topography and valley wind patterns. The Tianshan region experienced four main types of air masses: western (29.2%), northwestern (29.3%), northeastern (27.0%), and southern (14.5%). The northeastern air mass originating from the northern Tianshan Mountains exhibited the highest aerosol number concentration at 5449±3793 cm−3, while the southern air mass had the lowest at 1971±2087 cm−3. These differences are attributed to variations in air mass direction, movement paths, and the influence of the northern urban zone. At all supersaturation levels, the northeastern air mass also showed higher CCN number concentrations (which ranged from 100% to 150%) than the southern air mass.

     

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