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藏东南大气中多环芳烃的污染特征及来源分析

罗汉 张强 岳平 奚立宗 刘琴 尹春 王元兵 秦豪君 王琦 李宝梓 王劲松

罗汉, 张强, 岳平, 等. 2023. 藏东南大气中多环芳烃的污染特征及来源分析[J]. 大气科学, 47(3): 853−865 doi: 10.3878/j.issn.1006-9895.2212.22165
引用本文: 罗汉, 张强, 岳平, 等. 2023. 藏东南大气中多环芳烃的污染特征及来源分析[J]. 大气科学, 47(3): 853−865 doi: 10.3878/j.issn.1006-9895.2212.22165
LUO Han, ZHANG Qiang, YUE Ping, et al. 2023. Pollution Characteristics and Source Analysis of Polycyclic Aromatic Hydrocarbons in the Atmosphere of Southeast Tibet [J]. Chinese Journal of Atmospheric Sciences (in Chinese), 47(3): 853−865 doi: 10.3878/j.issn.1006-9895.2212.22165
Citation: LUO Han, ZHANG Qiang, YUE Ping, et al. 2023. Pollution Characteristics and Source Analysis of Polycyclic Aromatic Hydrocarbons in the Atmosphere of Southeast Tibet [J]. Chinese Journal of Atmospheric Sciences (in Chinese), 47(3): 853−865 doi: 10.3878/j.issn.1006-9895.2212.22165

藏东南大气中多环芳烃的污染特征及来源分析

doi: 10.3878/j.issn.1006-9895.2212.22165
基金项目: 第二次青藏高原综合科学考察项目2019QZKK0605,国家自然科学基金联合基金项目U2142208,国家自然科学基金重点项目42230611,甘肃省自然科学基金青年基金22JR5RA754,甘肃省气象局科研项目Ms2022-21
详细信息
    作者简介:

    罗汉,男,1988年出生,工程师,主要从事大气物理与大气环境相关研究。E-mail: luohan552200@126.com

    通讯作者:

    张强,E-mail: zhangqiang@cma.gov.cn

  • 中图分类号: X511

Pollution Characteristics and Source Analysis of Polycyclic Aromatic Hydrocarbons in the Atmosphere of Southeast Tibet

Funds: The Second Tibetan Plateau Comprehensive Scientific Expedition (Grant 2019QZKK0605), Program of National Natural Science Foundation Joint Fund of China (Grant U2142208), Key Program of National Natural Science Foundation of China (Grant 42230611), Youth Fund of Natural Science Foundation of Gansu Province (Grant 22JR5RA754), Scientific Research Project of Gansu Meteorological Bureau (Grant Ms2022-21)
  • 摘要: 为探究青藏高原东南部大气中多环芳烃(Polycyclic Aromatic Hydrocarbons,简称PAHs)的污染、源及输送特征,利用鲁朗地区(29.77°N,94.73°E)总悬浮颗粒物(Total Suspended Particles,简称TSP)和大气中的14种PAHs含量,结合同期气象环境数据进行了综合分析。结果表明,该地区TSP中PAHs和气相的PAHs质量浓度变化范围分别为0.22~5.05 ng m−3和0.83~63.75 ng m−3,平均值分别为2.13 ng m−3和11.33 ng m−3。薪柴和柴油的燃烧是污染的主要方式,汽油燃烧等其他排放为次要方式。PAHs来自本地污染和远距离传输(Long Range Transmission,简称LRT)共同的影响。本地污染在四季各个源地均不相同。冬春季本地污染大,源在东南及正南方,夏秋季受本地和外来输送共同作用,本地源在东南方且占比小,LRT占比大。LRT受西北气流、西风气流和西南气流三支气流影响,污染严重时西南气流占主导,西风气流次之,污染较轻时西风气流或西北气流占主导,西北气流所传输的污染最少。该研究结果加深了对藏东南区域PAHs变化、输送特征的认识,为该区域大气污染治理提供了理论依据。
  • 图  1  2008年11月至2011年9月(a)冬季、(b)夏季颗粒物中多环芳烃(PAHs)环数分布

    Figure  1.  Distributions of ring numbers of PAHs (Polycyclic Aromatic Hydrocarbons) in particular phases in (a) winter and (b) summer from November 2008 to September 2011

    图  2  图1,但为气相PAHs

    Figure  2.  Same as Fig. 1, but for gaseous-phase PAHs

    图  3  2008年11月至2011年9月(a–d)不同季节大气中PAHs及各组分的气粒占比

    Figure  3.  The ratios of gaseous to particular phase PAHs and components in (a–d) four seasons from November 2008 to September 2011

    图  4  2008年11月至2011年9月(a–d)不同季节粒相PAHs浓度与风速风向关系粒相

    Figure  4.  The relation diagrams of the concentration of PAHs in TSP with wind speed and direction in (a–d) four seasons from November 2008 to September 2011

    图  5  图4,但为气相PAHs

    Figure  5.  Same as Fig. 4, but for PAHs in gaseous

    图  6  采样点的后向12天气团轨迹及频率(a)2009年10月26日、(b)2009年8月17日、(c)2010年9月13日、(d)2009年1月15日(填色表示频率大小,计算方式为通过经纬度网格(0.125°×0.125°)的每日两条轨迹数除以轨迹总数)

    Figure  6.  Track and frequency of backward 12 days air mass at sampling points (a) October 26, 2009, (b) August 17, 2009, (c) September 13, 2010, (d) January 15, 2009(The color filling indicates the frequency, and the calculation method is through the longitude and latitude grid (0.125°×0.125°) divided by the total number of tracks)

    表  1  2008年11月至2011年9月不同季节总悬浮颗粒物(TSP)中PAHs质量浓度和质量分数

    Table  1.   Mass concentration and mass fraction of PAHs in TSP (Total Suspended Particulate matter) in different seasons from November 2008 to September 2011

    多环芳烃(PAHs)春季夏季秋季冬季
    质量浓度/pg m−3质量分数质量浓度/pg m−3质量分数质量浓度/pg m−3质量分数质量浓度/pg m−3质量分数
    苊烯(Acel)4.120.19%30.22%6.180.22%4.460.19%
    苊(Ace)8.330.38%4.940.37%12.020.43%9.990.43%
    菲(Phe)419.2419%367.4727.25%701.8225.05%391.5716.73%
    蒽(Ant)106.594.83%64.44.78%124.094.43%64.792.77%
    荧蒽(Fla)164.537.46%151.6711.25%320.7311.45%199.578.53%
    芘(Pyr)254.5911.54%180.9313.41%399.8214.27%298.1412.74%
    苯并(a)蒽(BaA)111.355.05%64.874.81%150.555.37%122.575.24%
    䓛(Chr)261.2911.85%180.0713.35%45516.24%360.515.41%
    苯并(b)荧蒽(BbF)166.887.57%695.12%119.454.2%139.725.97%
    苯并(k)荧蒽(BkF)207.569.41%82.936.15%153.455.48%221.719.47%
    苯并(a)芘(BaP)160.257.26%53.23.95%1214.32%186.647.98%
    茚并(1,2,3-cd)芘(IcdP)130.255.9%49.073.64%75.552.7%108.794.65%
    二苯并(a,h)蒽(DahA)19.880.9%7.330.54%13.820.49%15.430.66%
    苯并(ghi)苝(BghiP)1918.66%69.535.16%1485.28%216.149.24%
    ∑PAHs2205.85100%1348.4100%2801.47100%2340.03100%
    下载: 导出CSV

    表  2  表1,但为气相PAHs

    Table  2.   Same as Table 1, but for gaseous-phase PAHs

    多环芳烃(PAHs)春季夏季秋季冬季
    质量浓度/pg m−3质量分数质量浓度/pg m−3质量分数质量浓度/pg m−3质量分数质量浓度/pg m−3质量分数
    苊烯(Acel)8.450.18%2.360.03%15.360.1%53.621.39%
    苊(Ace)3.870.08%1.650.02%70.04%4.280.11%
    菲(Phe)234348.57%4404.3361.13%10329.2364.17%2019.0652.26%
    蒽(Ant)607.4412.59%958.7313.31%2011.6212.5%318.288.24%
    荧蒽(Fla)869.2518.02%964.2713.38%1913.6911.89%647.0616.75%
    芘(Pyr)686.2514.23%688.539.56%1414.318.79%591.2215.3%
    苯并(a)蒽(BaA)51.881.08%36.110.5%63.920.4%340.88%
    䓛(Chr)210.54.36%127.21.77%294.461.83%1533.965
    苯并(b)荧蒽(BbF)7.630.16%3.120.04%4.750.03%3.130.08%
    苯并(k)荧蒽(BkF)12.130.25%9.40.13%15.970.1%10.940.28%
    苯并(a)芘(BaP)11.560.24%4.330.06%10.990.07%12.780.33%
    茚并(1,2,3-cd)芘(IcdP)2.750.06%10.01%7.60.05%8.20.21%
    二苯并(a,h)蒽(DahA)0000
    苯并(ghi)苝(BghiP)90.19%3.620.05%7.570.05%7.940.21%
    ∑PAHs4823.71100%7204.66100%16096.47100%3863.5100
    下载: 导出CSV

    表  3  PAHs各单体组分间特征比及污染源

    Table  3.   Characteristic ratio of the PAHs monomer components and pollution sources

    各单体质量浓度比值
    Ant/(Ant+Phe)BaA/(BaA+Chr)IcdP/(IcdP+BghiP)BaP/BghiPBaP/IcdPBaA/ChrBbF/BkF
    木材0.11~0.25
    李英红等,2015
    0.41~0.57
    李英红等,2015
    秸秆0.12~0.24
    李英红等,2015
    0.38~0.52
    李英红等,2015
    焦化厂0.42~0.62
    李英红等,2015
    柴油燃烧0.23~0.63
    李英红等,2015
    0.3~0.4
    Bourotte et al., 2005
    约1.0
    Menichini et al., 1999
    0.2~0.4
    Simcik et al., 1999
    >0.5
    Park et al., 2002
    汽油燃烧~0.18
    Kavouras et al., 2001
    0.5~0.6
    Bourotte et al., 2005
    约0.4
    Menichini et al., 1999
    0.3~1.2
    Simcik et al., 1999
    1.1~1.5
    Dickhut et al., 2000
    冶炼0.9~6.6
    Akyüz and Çabuk,2008
    1.0~1.2
    Gschwend and Hites,1981
    3.5~3.9
    Masclet et al.,1987
    煤炭0.5~0.7
    Gschwend and Hites,1981
    2.5~2.9
    Masclet et al.,1987
    下载: 导出CSV

    表  4  鲁朗地区冷暖季各单体组分间特征比及污染源

    Table  4.   Characteristic ratio of the PAHs monomer components and pollution sources during cold and warm season in Lulang

    各单体质量浓度比值
    Ant/(Ant+Phe)BaA/(BaA+Chr)IcdP/(IcdP+BghiP)BaP/BghiPBaP/IcdPBaA/ChrBbF/BkF
    粒相冷季0.160.270.370.851.440.370.72
    粒相暖季0.150.250.360.811.360.340.77
    气相冷季0.170.190.41.452.110.240.5
    气相暖季0.170.190.511.341.300.240.31
    下载: 导出CSV
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  • 收稿日期:  2022-08-23
  • 录用日期:  2022-12-08
  • 网络出版日期:  2023-01-06
  • 刊出日期:  2023-05-15

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